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The use of Mt. Epomeo Green Tuff (MEGT) as a building stone is widespread on Ischia Island (Italy). We assess here the fire resistance of MEGT by thermally stressing samples to temperatures up to 1000 °C. Porosity and uniaxial compressive strength increase and decrease from 44% and 4.5 MPa at ambient temperature to 48% and 1.5 MPa following exposure to 1000 °C, respectively. Complementary thermogravimetric analysis, experiments that monitor acoustic emissions during heating/cooling, and microstructural observations highlight that these changes are the result of thermal microcracks, formed due to the dehydration and breakdown of zeolites and the thermal expansion/contraction of the glassy matrix. Although the stability of structures built from MEGT will be jeopardised at high temperature, a very low thermal diffusivity requires that fires must burn for many hours to compromise the strength of a typical dimension stone: tuffs are tough in the event of fire.
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